Tetrahedron Letters p. 6519 - 6522 (1999)
Update date:2022-08-10
Topics:
Toutchkine, Alexei
Clennan, Edward L.
The reactions of singlet oxygen with 2-chloroethyl ethyl sulfide and 3- chlorothiane are reported, In both cases elimination of HCl to produce α,β- unsaturated sulfoxides is observed. The experimental results implicate a hydroperoxy sulfonium ylide as a transition state or intermediate in an E2 or E1cb elimination, respectively.
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