Tetrahedron Letters p. 1805 - 1808 (1982)
Update date:2022-08-25
Topics:
Beckhaus, Hans-Dieter
Flamm, Manuela A.
Ruechardt, Christoph
The activation parameters for the homolytic cleavage of the central CC-bond in 1.1'-bidiamantane 5 and their comparison with corresponding data for 2.2.3.3-tetramethylbutane 6 together with the strain enthalpies of 5 and 6 are conclusive experimental evidence for the absence of appreciable strain in 1-adamantyl radicals 3.This supports predictions made on the basis of calculations using a recently developed force field for radicals.
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