Journal of Organometallic Chemistry p. 19 - 24 (1980)
Update date:2022-08-18
Topics:
Corriu, R. J. P.
Dabosi, G.
Martineau, M.
The electrochemical reduction peaks previously observed at about -0.4 V vs.SCE in the case of chloro- or bromo-silanes and -germanes actually refer to reduction of HCl or HBr formed by hydrolysis arising from traces of water in the solvent.This hydrolysis is catalysed by nucleophilic solvents.The electrochemical reduction of halo-silanes and -germanes in aprotic solvents giving the corresponding disilanes and digermanes is shown to be an irreversible process taking place at a low potential (-2 to -2.5 V vs.SCE).
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