Tetrahedron Letters p. 2329 - 2332 (1980)
Update date:2022-08-25
Topics:
Sakurai, Hideki
Sasaki, Koshi
Hosomi, Akira
Iodotrimethylsilane, prepared from hexamethyldisilane and iodine, reacts smoothly with oxiranes to give (2-iodoalkoxy)trimethylsilanes which can be converted to allylic alcohols with DBU in good yields.The whole conversion can be carried out in one-pot operation.
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