Tetrahedron p. 6941 - 6954 (1994)
Update date:2022-08-11
Topics:
Danieli, Bruno
Lesma, Giordano
Palmisano, Giovanni
Passarella, Daniele
Silvani, Alessandra
(+/-)-3-oxovincadifformine ethyl ester 14 has been synthesized through an intramolecular <4? + 2?> cycloaddition of the 3-oxosecodine 13 first prepared in turn from the enamide 10 by dehydrogenation with benzeneseleninic anhydride.An insight into the conversion of 10 into 13 was gained, resulting in the suggestion of a plausible mechanistic pathway.
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(2010)
