Journal of Physical Chemistry p. 1190 - 1194 (1984)
Update date:2022-08-11
Topics:
Danoczy, E.
Holly, S.
Jalsovszky, G.
Gal, D.
The H-bonded associates of α-phenylethyl hydroperoxide (HROOH) were investigated in CCl4, at various concentrations (0.788 X 1E-3 - 960 X 1E-3 M) and temperatures (22-75 deg C), by using IR spectroscopic methods.A very stable intramolecular OH..? bond was observed with a low enthalpy value.Above a concentration of 50 X 1E-3 M cyclic dimers and trimers were found, the latter with the lowest thermal stability.The corresponding thermodynamic parameters have been calculated.
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