Copper(II) Halide Catalyzed Cyclopropanation of Olefins Involving Dehydrobromination of Bromomalonic Ester by Amine

DOI: 10.1246/bcsj.55.2687

Source and publish data:

Bulletin of the Chemical Society of Japan p. 2687 - 2688 (1982)

Update date:2022-08-30

Topics:

Authors:

Kawabata, Nariyoshi

Yanao, Shinji

Yoshida, Jun-ichi

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1246/bcsj.55.2687

The reaction of olefins with bromomalonic ester and 1,8-diazabicyclo<5.4.0>undec-7-ene (DBU) proceeded in the presence of a catalytic amount of copper(II) halide to give 1,1-bis(alkoxycarbonyl)cyclopropane derivatives.DBU was converted into DBU-hydrobromi

Full text of DOI:10.1246/bcsj.55.2687

Products guided by the article

Product name:DIETHYL 2-PHENYL-1,1-CYCLOPROPANEDICARBOXYLATE

Cas No:3092-20-4

R&D Labs maybe for 3092-20-4

Chongqing Yawei Fine Chemical Co.,Ltd

Contact:0086-23-62849407

Address:Ziyou village, Nanquan town, Banan district, Chongqing China
Shandong Yubin Chemical CO.,LTD

website:http://www.yukaichem.com/en.html

Contact:+86-536-8865336

Address:binhai economic development zone，262737 shangdong，china
Chengdu Chengnuo New-Tech Co., Ltd

Contact:0086-028-85749078

Address:4 Jiuyang road,Jiulong industrial port,Chengdu, China
Hubei Xinghuo Chemical Co., Ltd.,

Contact:13925817279 13907299441

Address:Xinghuo Fine Chemistry Industrial Park, Xiaochang County, Hubei Province, China
Shuanghe Bio-Technology Limited(expird)

Contact:+86-571-61710758,18968016640

Address:Jinqiao north road 916# Fuyang

Relevant to this article

Uncovering potential interspecies signaling factors in plant-derived mixed microbial culture

Doi:10.1016/j.bmc.2021.116254
(2021)
The Semireduced Mechanism for Nitric Oxide Reduction by Non-Heme Diiron Complexes: Modeling Flavodiiron Nitric Oxide Reductases

Doi:10.1021/jacs.7b11464
(2018)
Convergent Synthesis of the Dihydropyran Core Containing the C1-C15 Subunit of Sorangicin A Employing Gold(I)-Catalyzed Cyclization of an Allenic Alcohol

Doi:10.1021/acs.joc.6b01743
(2016)
Synthesis and antitumor activity of novel steroidal imidazolium salt derivatives

Doi:10.1016/j.ejmech.2019.02.025
(2019)
Sterically shielded secondary N-tritylamines and N-tritylamide bases, readily available and useful synthetic reagents

Doi:10.1016/S0040-4039(00)00240-9
(2000)
A novel one-pot synthesis of N,6-disubstituted 1,3,5-triazine-4,6-diamines from isothiocyanates and amidines

Doi:10.1016/j.tetlet.2006.11.069
(2007)

Article Doi