
Tetrahedron Letters p. 1363 - 1364 (1995)
Update date:2022-08-17
Topics:
Bernardi, Anna
Karamfilova, Katia
Boschin, Giovanna
Scolastico, Carlo
The conjugate addition of t-butylpropionate silylketeneacetal 2 to 2-carboxycyclopentenones 3a-b promoted by TADDOL-derived Ti chlorides gives the ketoacid 6 with excellent d.e. and e.e. up to 47percent.
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