Aziridination of α,β-unsaturated esters bearing allylic hydroxy groups with 3-acetoxyaminoquinazolinones: Evidence for a mechanism comprising Michael addition-SN2 nucleophilic displacement of acetoxy for aziridination of α,β-unsaturated esters

DOI: 10.1039/P19960001951

Source and publish data:

Journal of the Chemical Society. Perkin transactions I p. 1951 - 1959 (1996)

Update date:2022-08-11

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Authors:

Atkinson, Robert S.

Williams, Paul J.

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Article abstract of DOI:10.1039/P19960001951

Aziridinations of the allylic alcohol-bearing α,β-unsaturated esters 6 and 7 and their corresponding acetates 8 and 9 have been carried out under standard conditions using 3-acetoxyaminoquinazolinone 2. Whereas the preferred sense of diastereoselectivity

Full text of DOI:10.1039/P19960001951

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