Bulletin of the Chemical Society of Japan p. 3212 - 3214 (1992)
Update date:2022-08-16
Topics:
Mazaki, Hitoshi
Watanabe, Tadashi
Takahashi, Terumi
Struck, Andreas
Scheer, Hugo
A significant difference in the pheophytinization rates among four C132-epimer pairs of chlorophylls is explained in terms of the inductive effects of ring substituents, and/or a strain at the macrocycle core due to the C132 stereochemistry.The rate-determining step appears to involve two protons at high
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