Chemistry Letters p. 43 - 46 (1981)
Update date:2022-08-28
Topics:
Boyer, Joseph H.
Ramakrishnan, V. T.
Srinivasan, K. G.
Spak, A. J.
Irradiation in the presence of triplet oxygen polymerized both 2,4-dimethoxyphenyl and cyclohexyl isocyanide and photoautoxidized each into the corresponding isocyanate.The aryl, but not the alicyclic, isocyanide also photoisomerized into a cyanide.The consumption of an isocyanide was enhanced in the presence of certain aromatic hydrocarbons, e. g., naphthalene and phenanthrene, but was diminished in the presence of pyrene.Two bisisocyanides were unaffected by the presence of oxygen during irradiation.
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Doi:10.1246/bcsj.46.3179
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