Journal of the Chemical Society. Chemical communications p. 147 - 148 (1988)
Update date:2022-08-10
Topics:
King, James F.
Lam, Joe Y. L.
Skonieczny, Stanislaw
The cyclization of o-chloromethylbenzylamine to dihydroisoindole has an effective concentration of 8.3 M (in CD3OD at 21 deg C); this very low value for a cyclization to a benzo-fused five-membered ring is ascribed to lessend conjugation in the transition state as compared to that of the model reaction, and is relevant to both the synthesis of rings and the application of effective concentrations in obtaining evidence of mechanism.
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