
Journal of the Chemical Society. Chemical communications p. 1031 - 1032 (1983)
Update date:2022-08-23
Topics:
Pauls, Henry W.
Fraser-Reid, Bert
The imidate ester obtained from the reaction of methyl 2,3,6-trideoxy-α-L-threo-hex-2-enopyranoside with trichloroacetonitrile undergoes iodonium ion-induced cyclisation, and the dihydroxazole product is subjected to reductive dehalogenation to give a protected form of daunosamine.
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