Synthesis p. 1005 - 1007 (1990)
Update date:2022-08-11
Topics:
Chauncey
Grundon
1-Methyl-3-methylene-2,4(1H,3H)-quinolinedione (2), prepared from 4-hydroxy-1,3-dimethyl-2(1H)-quinolinone (1) and 2,3-dichloro-5,6-dicyano-1,4-benzoquinone (DDQ) gives the dimer 3. Compound 2 also reacts in situ with 2,2-dimethyl-2H-1-benzopyran and with isopropenyl acetate to give Diels-Alder cycloaddition products.
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