Journal of the American Chemical Society p. 4934 - 4943 (1982)
Update date:2022-08-29
Topics:
White, Robert L.
Spenser, Ian D.
Radioactivity from D-<1-14C>-, D-<2-14C>-, and D-<6-14C>glucose, from D-<1-14C>fructose, and from <1-14C>glycerol is incorporated nonrandomly into the C5 chain of the thiazole moiety of thiamin in Saccharomyces cerevisiae.The incorporation pattern leads to inference that the C5 chain is derived from a 2-pentulose, which is generated from the hexose precursors by the oxidative as well as by the nonoxidative pentose phosphate pathway.A chemically rational scheme for the biogenesis of the thiazole moiety of thiamin is presented.
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