Journal of Fluorine Chemistry p. 47 - 56 (1983)
Update date:2022-08-11
Topics:
Benefice, Sylvie
Blancou, Hubert
Commeyras, Auguste
Reactivity of perfluoroalkyl iodides (RFI) and perfluoroalkyl-2 iodide-1 ethanes (RFCH2CH2I), in the presence of a zinc-copper couple, in a particular dissociating solvent, "the sulfolane", is described.RFI and RFCH2CH2I react via an organometallic route to give perfluoroorganozinc compounds.Then, RFCH2CH2I react with the sulfolane solvent.In this case, a diperfluoroalkyl-2 ethyl-1 sulfone (RFCH2CH2)2SO2 is obtained.
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