Journal of Fluorine Chemistry p. 257 - 276 (1989)
Update date:2022-08-16
Topics:
Prokop, H. W.
Zhou, H-J.
Xu, S-Q.
Wu, C-H.
Chuey, S. R.
Liu, C. C.
The electrochemical fluorination of octanoyl chloride to produce perfluorooctanoyl fluoride in anhydrous hydrogen fluoride was investigated.The study was carried out in a microprocessor-aided modified Simons reactor system using a Cu/CuF2 reference electrode.The formation of polymeric tar at the anode surface was limited by the addition of a mercaptan compound and by constant current density operation.Continuous operation was achieved through frequent additions of a solution of hydrogen fluoride and reactant.Conversion of reactant to perfluorinated products was improved to 80 percent with good selectivity.Experimetnal results of this investigation are presented and discussed.
View More
Shandong Dayi Chemical Co., Ltd.
website:http://www.dayi.com.cn
Contact:+86- 535-7388728. 15306386031
Address:No 1 Danya west road, Laiyang City, Shandong province
Jinan Hongfangde Pharmatech Co.,Ltd
Contact:86-531-88870908
Address:F Bldg. West Unit North Area of Univ. Tech. Garden Xinyu Rd. Jinan New & High Tech Industry Development Zone Shandong, China
Contact:0086 371 65711996
Address:Jalan 4/3, Kawasan Perindustrian Serendah, 48000 Rawang,
Contact:+86-10-62651721
Address:29 Yongxing Road, Daxing District,Beijing China
SuZhou Bichal Biological Technology CO.,LTD
Contact:+86-512-68051130
Address:NO.32 huoju road HI-TECH Industrial development zone SuZhou China
Doi:10.1080/00397911.2014.944268
(2014)Doi:10.1039/c5ra22508f
(2016)Doi:10.1109/MIC.2000.845395
(1901)Doi:10.1021/ie50471a025
(1949)Doi:10.1007/BF01912080
(1990)Doi:10.1039/c8dt04058c
(2019)
