Journal of Fluorine Chemistry p. 257 - 276 (1989)
Update date:2022-08-16
Topics:
Prokop, H. W.
Zhou, H-J.
Xu, S-Q.
Wu, C-H.
Chuey, S. R.
Liu, C. C.
The electrochemical fluorination of octanoyl chloride to produce perfluorooctanoyl fluoride in anhydrous hydrogen fluoride was investigated.The study was carried out in a microprocessor-aided modified Simons reactor system using a Cu/CuF2 reference electrode.The formation of polymeric tar at the anode surface was limited by the addition of a mercaptan compound and by constant current density operation.Continuous operation was achieved through frequent additions of a solution of hydrogen fluoride and reactant.Conversion of reactant to perfluorinated products was improved to 80 percent with good selectivity.Experimetnal results of this investigation are presented and discussed.
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