One-pot electrochemical generation of a porphyrin dimer with a bis(diphenylphosphonium)acetylene bridge

DOI: 10.1039/cc9960002007

Source and publish data:

Chemical Communications p. 2007 - 2008 (1996)

Update date:2022-08-17

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Authors:

Ruhlmann, Laurent

Giraudeau, Alain

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Article abstract of DOI:10.1039/cc9960002007

The electrochemical oxidation of zinc tetraphenylporphyrin in the presence of bis(diphenylphosphino)acetylene leads to the formation of a β-bridged dimer using 0.5 equiv. of Lewis base per mole of [Zn(tpp)]; a mixture of monomer and dimer is observed when stoichiometric amounts or an excess of diphosphine was used.

Full text of DOI:10.1039/cc9960002007

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