Chemical Communications p. 2007 - 2008 (1996)
Update date:2022-08-17
Topics:
Ruhlmann, Laurent
Giraudeau, Alain
The electrochemical oxidation of zinc tetraphenylporphyrin in the presence of bis(diphenylphosphino)acetylene leads to the formation of a β-bridged dimer using 0.5 equiv. of Lewis base per mole of [Zn(tpp)]; a mixture of monomer and dimer is observed when stoichiometric amounts or an excess of diphosphine was used.
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