Acyclic Diastereoselection in the Wittig Sigmatropic Rearrangement of a Series of Isomeric Crotyl Ethers. A Conceptual Model for the Transition-State Geometry

DOI: 10.1021/jo00150a033

Source and publish data:

Journal of Organic Chemistry p. 279 - 281 (1983)

Update date:2022-08-18

Topics:

Authors:

Mikami, K.

Kimura, Y.

Kishi, N.

Nakai, T.

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1021/jo00150a033

The levels of diastereoselection in a broad range of <2,3> Wittig Variations with different substituents on the carbanion termini have been evaluated and permit us to propose a reasonable model for the transition-state geometry.

Full text of DOI:10.1021/jo00150a033

Products guided by the article

Product name:1,5-Hexadien-3-ol, 4-methyl-1-phenyl-, (1E)-

Cas No:339591-35-4

R&D Labs maybe for 339591-35-4

CGeneTech (Suzhou, China) Co., Ltd.

Contact:+86-512-62956962

Address:Room 101，Bld C11,218 Xinghu Rd.,Suzhou industrial Park
Guangxi Nanning Guangtai Agriculture Chemical Co.,Ltd

Contact:+86-771-2311266

Address:Room703,Building12, Software Park Phase II,NO.68,Keyuan Road,Nanning City,Guangxi,China
Changzhou Ruiping Chemical Co., Ltd

website:http://www.wishchem.com

Contact:+86-519-82324280

Address:No.288-1 Huacheng Road, Jintan
Qingdao Kingway Pharmtech Co., Ltd.

Contact:86-532-87118899

Address:No. 88, Middle Haixi Road, Jiaonan City, Qingdao, China
HUNAN CHEMAPI BIOLOGICAL TECHNOLOGY CO.,LTD.

Contact:+86-186-02659358

Address:1004, building 3, Wanke Jinsemaitianyuan, 498 Guitang Road, Yuhua District, Changsha City, Hunan Province, China

Relevant to this article

Highly phosphorescent organopalladium(ii) complexes with metal-metal-to-ligand charge-transfer excited states in fluid solutions

Doi:10.1039/c9dt02525a
(2019)
Synthesis and characterisation of aluminophosphate-based zeotype materials prepared with α,ω-bis(N-methylpyrrolidinium)alkane cations as structure-directing agents

Doi:10.1039/b706206k
(2007)
Side-chain alkylation of toluene with methanol to styrene over cesium ion-exchanged zeolite X modified with metal borates

Doi:10.1016/j.apcata.2012.08.003
(2012)
Manniosides B-F, five new triterpenoid saponins from the leaves of Schefflera mannii (Hook.f.) Harms

Doi:10.1016/j.carres.2021.108279
(2021)
The synthesis of new derivatives of 1-β-D-arabinofuranosylcytosine

Doi:10.1248/cpb.26.981
(1978)
Doi:10.1007/BF01363027
(1870)

Article Doi