Acyclic Diastereoselection in the Wittig Sigmatropic Rearrangement of a Series of Isomeric Crotyl Ethers. A Conceptual Model for the Transition-State Geometry

DOI: 10.1021/jo00150a033

Source and publish data:

Journal of Organic Chemistry p. 279 - 281 (1983)

Update date:2022-08-18

Topics:

Authors:

Mikami, K.

Kimura, Y.

Kishi, N.

Nakai, T.

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Article abstract of DOI:10.1021/jo00150a033

The levels of diastereoselection in a broad range of <2,3> Wittig Variations with different substituents on the carbanion termini have been evaluated and permit us to propose a reasonable model for the transition-state geometry.

Full text of DOI:10.1021/jo00150a033

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