
Tetrahedron Letters p. 61 - 64 (1981)
Update date:2022-08-17
Topics:
Bougeois, Jean-Luc
Stella, Lucien
Surzur, Jean-Marie
Extremely high stereospecificity (up to 100percent diastereoisomeric purity) can be obtained for the metallic salts induced radical cyclisation of the cis and trans 1-methyl 4-hexenyl N-chloroamines.A possible mechanism for the highly effective trans-addition using metal-complexed aminyl radical is proposed.
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Doi:10.1039/c39870000773
(1987)Doi:10.1111/cbdd.12650
(2016)Doi:10.1039/P19720000472
(1972)Doi:10.1016/S0040-4039(00)96393-7
(1987)Doi:10.1016/S0022-328X(98)00483-5
(1998)Doi:10.1007/BF01516540
(1881)