TOTAL STEREOSPECIFICITY IN FREE RADICAL INTRAMOLECULAR ADDITION: CYCLISATION OF CIS AND TRANS 1-METHYL 4-HEXENYL N-CHLOROAMINES BY MEANS OF METALLIC SALTS

DOI: 10.1016/0040-4039(81)80041-X

Source and publish data:

Tetrahedron Letters p. 61 - 64 (1981)

Update date:2022-08-17

Topics:

Authors:

Bougeois, Jean-Luc

Stella, Lucien

Surzur, Jean-Marie

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/0040-4039(81)80041-X

Extremely high stereospecificity (up to 100percent diastereoisomeric purity) can be obtained for the metallic salts induced radical cyclisation of the cis and trans 1-methyl 4-hexenyl N-chloroamines.A possible mechanism for the highly effective trans-addition using metal-complexed aminyl radical is proposed.

Full text of DOI:10.1016/0040-4039(81)80041-X

Products guided by the article

Product name:ethyl cis-4-hexenoate

Cas No:34495-73-3

R&D Labs maybe for 34495-73-3

SJZ Chenghui Chemical Co., Ltd.

Contact:86-311-87713916

Address:no.368 youyi north avenue
Hangzhou Mole's Science & Technology Co.,Ltd.(expird)

Contact:+86-571-56880228

Address:15F Guodu development Building, NO.182 Zhaohui Road
Feis International Trade Co,. Ltd

Contact:13961823444-18235944442

Address:Wuxi jiangsu
Lanling Hongchuang Flame Retardant Co., Ltd.

Contact:+86-531-68858132

Address:East Huafeichang Road, Cangshan County, Linyi, Shandong, China (Mainland)
YingYing Pharmaceutical Co.,Ltd

Contact:86-18854126208

Address:55#, yingxiongshan road

Relevant to this article

Poly(Pyrrole-Phenothiazine) Modified Electrodes. Application as Photoelectrodes via a Charge Transfer Complex

Doi:10.1039/c39870000773
(1987)
Rational Design of Glycomimetic Compounds Targeting the Saccharomyces cerevisiae Transglycosylase Gas2

Doi:10.1111/cbdd.12650
(2016)
Sporidesmins. 8. Ovine ill-thrift in Nova Scotia. 3. The characterisation of chetomin a toxic metabolite of Chaetomium cochliodes and Chaetomium globosum.

Doi:10.1039/P19720000472
(1972)
Me3SiCl-NaI-CH3CN AS AN EFFICIENT AND PRACTICAL REDUCING AGENT FOR BENZYLIC ALCOHOLS

Doi:10.1016/S0040-4039(00)96393-7
(1987)
Electronic spectrum and photoreactivity of dichloro(1,5-cyclooctadiene)-palladium(II)

Doi:10.1016/S0022-328X(98)00483-5
(1998)
Doi:10.1007/BF01516540
(1881)

Article Doi