Journal of the Chemical Society, Faraday Transactions 1: Physical Chemistry in Condensed Phases p. 2271 - 2276 (1981)
Update date:2022-08-30
Topics:
Marshall, Roger M.
Shahkar, Gholamreza
A new method of data treatment is described which permits the measurement of the rate constant for the reaction CH3+H2 -> CH4+H (2) without any assumption of a value for the rate constant for methyl recombination.Experiments in which azomethane was pyrolysed in a large excess of hydrogen were carried out in the ranges 584-671 K and 5-26 Torr total pressure.The results can be expressed in the form log(k2/cm3mol-1s-1)=11.70-44 kJ mol-1/(2.3 RT).The conditions for which the theory of the method is valid are discussed.
View Morejiangsu senxuan pharmaceutical and chemical co.,ltd
Contact:86-523-87982810
Address:hongqiao industrial zone,taixing,jiangsu china
Yurui(Shanghai)Chemical Co.,Ltd
Contact:0086 21-50456736
Address:No.3188 Xiupu Road,Shanghai
Contact:86-532-68629711 13780605697
Address:NO 220 YANAN 3 ROAD,(POST ADMINISTRATION BUILDING),QINGDAO,CHINA
SHIJIAZHUANG HENRYTE CHEMICALS CO,.LTD(expird)
Contact:+86-311-85208698 311-80837698
Address:NO.166, yuhua west road, SHIJIAZHUANG, China
Lanling Hongchuang Flame Retardant Co., Ltd.
Contact:+86-531-68858132
Address:East Huafeichang Road, Cangshan County, Linyi, Shandong, China (Mainland)
Doi:10.1002/ejoc.201500277
(2015)Doi:10.1016/j.bmcl.2017.01.052
(2017)Doi:10.1021/acs.joc.6b02735
(2017)Doi:10.1016/j.cplett.2007.05.033
(2007)Doi:10.1016/j.ejmech.2020.112437
(2020)Doi:10.1021/jacs.7b09358
(2017)
