Synthesis p. 73 - 77 (1995)
Update date:2022-08-11
Topics:
Page, Philip C. Bulman
Shuttleworth, Stephen J.
McKenzie, Michael J.
Schilling, Mark B.
Tapolczay, David J.
syn- and anti-2-Acyl-2-alkyl-1,3-dithiane 1-oxides, when treated with trifluoroacetic anhydride, undergo either an unexpected Pummerer rearrangement or equilibration in near quantitative yield, depending upon the reaction conditions; 2-acyl-1,3-dithiane 1
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