THE VAPOUR PRESSURES AND EXCESS FREE ENERGIES OF MIXING OF THE SYSTEMS HEXAFLUOROBENZENE-CARBON TETRACHLORIDE AND HEXAFLUOROBENZENE-PERFLUOROMETHYLCYCLOHEXANE

DOI: 10.1016/S0022-1139(00)81462-1

Source and publish data:

Journal of Fluorine Chemistry p. 267 - 278 (1980)

Update date:2022-08-29

Topics:

Authors:

Patrick, C. R.

Tomes, F.

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Article abstract of DOI:10.1016/S0022-1139(00)81462-1

The vapour pressures of liquid mixtures of hexafluorobenezene with carbon tetrachloride and of hexafluorobenzene with perfluoromethylcyclohexane (tetradecafluoromethylcyclohexane) have been measured in the range of temperature 20-50 deg C, in a static system.These have been used to obtain the excess free energies of the mixtures.Both mixtures show large positive deviations from thermodynamic ideality, and also show azeotropic behaviour.

Full text of DOI:10.1016/S0022-1139(00)81462-1

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