THE CHEMISTRY OF DIACYL PEROXIDES - VIII. THE REACTIONS BETWEEN POLYFLUORODIACYL PEROXIDES AND 2-NITRO-2-NITROSOPROPANE--GENERATION OF BIS(POLYFLUOROALKYL) NITROXIDES

DOI: 10.1016/S0022-1139(00)81958-2

Source and publish data:

Journal of Fluorine Chemistry p. 597 - 606 (1987)

Update date:2022-08-11

Topics:

Authors:

Zhao, Cheng-Xue

Chen, Guo-Fei

Jiang, Xi-Kui

Wang, Xian-Shan

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/S0022-1139(00)81958-2

Thermal decomposition of 2-nitro-2-nitrosopropane (4) in F113 (CCl2F-CClF2) solution involves C-NO bond fission and forms acetone as the major product.In the presence of polyfluorodiacyl peroxide (3), the oxidation of 4 by 3 to 2,2-dinitropropane (5) is the predominant reaction and bis(polyfluoroalkyl) nitroxide (1) is generated as one of the by-products.

Full text of DOI:10.1016/S0022-1139(00)81958-2

Products guided by the article

Product name:PERFLUOROHEXANE

Cas No:355-42-0

R&D Labs maybe for 355-42-0

MINS GROUP CO.,LIMITED

Contact:18669908765

Address:Zibo City, Shandong Province, P.R.China
Phantom-pharma

Contact:

Address:
Lanzhou huibang biological chemical technology Co., LTD

Contact:0931-7843964

Address:NO.2011,Yannan Road,Chengguan,
ShenZhen InnoSyn Biotech Co.,Ltd

website:http://www.innosyns.com

Contact:+86-755-28351685

Address:Floor 5 & 6, Building A1, HAIKEXING Strategic Innovative Industrial Park, 16 BaoShan Road, PingShan District
Guilin Zhenda Bio-Tech Co., Ltd.

Contact:86-773-3568977

Address:-Yangtang shangshui industry park, Lingui county,

Relevant to this article

Control of the dual emission from a thermally activated delayed fluorescence emitter containing phenothiazine units in organic light-emitting diodes

Doi:10.1039/c8ra10393c
(2019)
Doi:10.1007/BF01540839
()
Attachment of a substituted t-butyl group to the N-atom of aromatic amines with 1-acyl-2,2-dimethylaziridines

Doi:10.1002/ardp.19933260402
(1993)
Enantioselective reduction of acetophenone with 1,3,2-oxazaborolidines derived from ephedrine, pseudoephedrine, and phenylglycine

Doi:10.1016/S0957-4166(00)86005-X
(1993)
Doi:10.1007/s00276-001-0263-z
(1955)
Site-directed mutagenesis switching a dimethylallyl tryptophan synthase to a specific tyrosine C³-prenylating enzyme

Doi:10.1074/jbc.M114.623413
(2015)

Article Doi