THE CHEMISTRY OF DIACYL PEROXIDES - VIII. THE REACTIONS BETWEEN POLYFLUORODIACYL PEROXIDES AND 2-NITRO-2-NITROSOPROPANE--GENERATION OF BIS(POLYFLUOROALKYL) NITROXIDES

DOI: 10.1016/S0022-1139(00)81958-2

Source and publish data:

Journal of Fluorine Chemistry p. 597 - 606 (1987)

Update date:2022-08-11

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Authors:

Zhao, Cheng-Xue

Chen, Guo-Fei

Jiang, Xi-Kui

Wang, Xian-Shan

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Article abstract of DOI:10.1016/S0022-1139(00)81958-2

Thermal decomposition of 2-nitro-2-nitrosopropane (4) in F113 (CCl2F-CClF2) solution involves C-NO bond fission and forms acetone as the major product.In the presence of polyfluorodiacyl peroxide (3), the oxidation of 4 by 3 to 2,2-dinitropropane (5) is the predominant reaction and bis(polyfluoroalkyl) nitroxide (1) is generated as one of the by-products.

Full text of DOI:10.1016/S0022-1139(00)81958-2

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