Evidence for Hydrogen Bonding in Solution of 1-Ethyl-3-methylimidazolium Halides, and its Implications for Room-temperature Halogenoaluminate(III) Ionic Ligands

DOI: 10.1039/DT9940003405

Source and publish data:

Journal of the Chemical Society, Dalton Transactions p. 3405 - 3414 (1994)

Update date:2022-08-16

Topics:

Authors:

Avent, Anthony G.

Chaloner, Penelope A.

Day, Martin P.

Seddon, Kenneth R.

Welton, Thomas

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1039/DT9940003405

Multinuclear NMR spectroscopy and conductivity measurements showed that the 1-ethyl-3-methylimidazolium cation, (1+), not only forms strong hydrogen bonds (using all three ring protons H², H⁴ and H⁵) with halide ions in polar molecular solvents (e.g. ethanenitrile) and ionic liquids, but that it exists in a quasi-molecular state, X, in non-polar solvents (e.g. trichloro- and dichloromethane), showing a conventional aromatic stacking phenomenon.

Full text of DOI:10.1039/DT9940003405

View Online / Journal Homepage / Table of Contents for this issue

View Online

Products guided by the article

Product name:1-ETHYL-3-METHYLIMIDAZOLIUM IODIDE

Cas No:35935-34-3

R&D Labs maybe for 35935-34-3

chemonlinephramacistdepot

Contact:86-607-68073220

Address:1 ave na road jiahua st
Nanjing Duly Biotech Co., Ltd

website:http://www.dulynet.com/

Contact:025-84699383 -8003

Address:Room 503, Building 2, Chuangxinhui, No. 61 Wenjing Road, High-tech Development Zone, Pukou District, Nanjing City, Jiangsu Province Nanjing, Jiangsu
Wuxi Zuping Food Science And Technology Co.,LTD.

Contact:+86-510-87210822

Address:Guanlin town
Chengdu Herbpurify Co., Ltd

website:http://www.herbpurify.com

Contact:0086-028-85249238

Address:Room709-C1,Incubator Building, Tianfu Life Science Park No.88,Keyuan Road,Gaoxin district,Chengdu City,Sichuan Prov,China
Nanjing Samwon International Limited

Contact:+86-25-84873444

Address:1108, BLDG B, New Century Plaza, No 1, South Taiping Rd.,

Relevant to this article

Doi:10.1016/0022-328X(86)80044-4
(1986)
MECHANISM OF THE REACTION OF DIPHENYLPHOSPHINODITHIOIC ACID WITH NITRILES

Doi:10.1016/S0040-4039(01)90460-5
(1981)
Intramolecular sensitization within steroids: Excited-state interaction of C-17 α and β carbon-bromine bonds with a C-6 carbonyl group

Doi:10.1139/v03-055
(2003)
A highly efficient artificial light-harvesting system with two-step sequential energy transfer based on supramolecular self-assembly

Doi:10.1039/d0ta03169k
(2020)
Gold-Catalyzed Dearomative Spirocyclization of N-Aryl Alkynamides for the Synthesis of Spirolactams

Doi:10.1021/acs.joc.7b03125
(2018)
New pnictides with the CaAl₂Si₂ type structure and the stability range of this type

Doi:10.1515/znb-2002-1112
(2002)

Article Doi