A SEARCH FOR SINGLE-ELECTRON TRANSFER (SET) MECHANISMS IN THE REACTION OF 1,3-DITHIANYL- AND 1,3-OXATHIANYLLITHIUMS WITH PRIMARY HALIDES

DOI: 10.1016/S0040-4039(00)98343-6

Source and publish data:

Tetrahedron Letters p. 1927 - 1930 (1985)

Update date:2022-08-17

Topics:

Authors:

Juaristi, Eusebio

Gordillo, Barbara

Aparicio, Dulce Ma.

Bailey, William F.

Patricia, Jeffrey J.

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Article abstract of DOI:10.1016/S0040-4039(00)98343-6

The reaction of 1,3-dithianyl-, 2-methyl-1,3-dithianyl- and 1,3-oxathianyllithium with 6-halo-1-hexenes affords the products expected from a S_N2 (rather than SET) mechanism.

Full text of DOI:10.1016/S0040-4039(00)98343-6

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