Tetrahedron Letters p. 4289 - 4292 (1993)
Update date:2022-08-12
Topics:
Abu-Yousef
Hynes
Harpp
When triphenylmethanesulfenyl chloride (1) (or its thio homolog 2) are treated with various bicycles, 1,2 addition reactions take place. Final products occur via an episulfide intermediate. The stereochemistry of addition has been determined by x-ray analysis. Finally, evidence has been obtained for the delivery of diatomic sulfur, likely via intermediate 3.
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