Journal of Fluorine Chemistry p. 217 - 226 (1993)
Update date:2022-08-10
Topics:
Benefice-Malouet, S.
Blancou, H.
Commeyras, A.
The reactivity of perfluoroalkyl iodide in the presence of a zinc-copper metal couple and a radical initiator in DMF, has been investigated.This led to the formation of a mixture of N,N-dimethyl perfluoroalkylamide and perfluoroalkyl aldehyde.After studying the influence of different reaction parameters, the perfluoroalkyl aldehyde formation has been optimized to high yield (over 90percent).
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