Silver(I) Salts as One-electron or Two-electron Oxidants in their Reactions with 2(η-C5H5)2(CO)4-n(CNMe)n> Derivatives (n = 0-2). The Effect of Varying the Reaction Solvent

Article abstract of DOI:10.1039/c39830000263

In tetrahydrofuran AgNO3 acts as a two-electron oxidant and cleaves to give a mixture of and via a detectable adduct, but in acetonitrile it acts as a one-electron oxidant to give NO3 and the ^. radical which then dimerises or reacts with added radical traps.

Full text of DOI:10.1039/c39830000263

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