A New Chiral Cyclophane Derived from 1,1'-Binaphthol and Benzylviologen

DOI: 10.1016/0040-4039(95)01593-7

Source and publish data:

Tetrahedron Letters p. 7599 - 7602 (1995)

Update date:2022-08-29

Topics:

Authors:

Deng, Nanlin

Marwaha, Vijay Rai

Garcia, Maurie E.

Benesi, Alan

Mallouk, Thomas E.

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Article abstract of DOI:10.1016/0040-4039(95)01593-7

A new chiral cyclophane, with a binding cavity defined by the 1,1'-binaphthyl "minor groove" and a strongly ?-accepting 4,4'-bipyridinium dication, has been synthesized.It self-associates in solution (K=(4.1+/-1.6)*10² M^-1), and forms charge-transfer complexes with strong ?-electron donors.

Full text of DOI:10.1016/0040-4039(95)01593-7

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