New total synthesis of (+)-cystothiazole A based on palladium-catalyzed cyclization-methoxycarbonylation

DOI: 10.1016/S0040-4020(03)00300-4

Source and publish data:

Tetrahedron p. 2679 - 2685 (2003)

Update date:2022-08-11

Topics:

Authors:

Kato, Keisuke

Sasaki, Takamitsu

Takayama, Hiroyuki

Akita, Hiroyuki

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Article abstract of DOI:10.1016/S0040-4020(03)00300-4

Palladium-catalyzed cyclization-methoxycarbonylation of (2R,3S)-3-methylpenta-4-yne-1,2-diol (6) derived from (2R,3S)-epoxy butanoate 7 followed by methylation gave the tetrahydro-2-furylidene acetate (-)-10, which was converted to the left-half aldehyde

Full text of DOI:10.1016/S0040-4020(03)00300-4

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Product name:4-Thiazolecarboxamide,2-(1-methylethyl)-(9CI)

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