Remote substituent control of the regioselectivity of the aryl- and vinylpalladation of 7-oxabicyclo[2.2.1]heptenes

DOI: 10.1016/0040-4039(96)00237-7

Source and publish data:

Tetrahedron Letters p. 2225 - 2228 (1996)

Update date:2022-08-25

Topics:

Authors:

Montalbetti, Christian

Savignac, Monique

Genet, Jean-Pierre

Roulet, Jean-Michel

Vogel, Pierre

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Article abstract of DOI:10.1016/0040-4039(96)00237-7

Pd-catalyzed arylations of 2-exo-cyano-7-oxabicyclo[2.2.1]hept-5-en-2-endo-yl acetate and 7-oxabicyclo[2.2.1]hept-5-en-2-one are regio- and stereoselective giving products of H₂ (HCOOH) and Me₃SiC ≡ CH coupling in which the aryl grou

Full text of DOI:10.1016/0040-4039(96)00237-7

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