Chemistry Letters p. 155 - 156 (1995)
Update date:2022-08-11
Topics:
Okuhara, Toshio
Nishimura, Toru
Misono, Makoto
The pore size of acidic Cs salts (CsxH3-xPW12O40) was precisely controlled by the Cs content.Cs2.2H0.8PW12O40 possesses micropores in the range from 6.2 to 7.5 Angstroem (in diameter) and exhibits efficient shape selective catalysis toward decomposition of ester, dehydration of alcohol, and alkylation of aromatics in liquid-solid system.This is the first example of shape-selective solid superacid.
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