Steric Control between Neutral Metal-Only Lewis Pairs and Metal-Stabilized Gallenium and Gallinium Cations

DOI: 10.1021/acs.organomet.6b00045

Source and publish data:

Organometallics p. 1002 - 1007 (2016)

Update date:2022-08-29

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Authors:

Braunschweig, Holger

Dewhurst, Rian D.

Schneider, Christoph

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Article abstract of DOI:10.1021/acs.organomet.6b00045

Reaction of a series of zerovalent Fe Lewis bases with Lewis acid GaCl₃ leads to both conventional, neutral metal-only Lewis pairs in the case of small metal complexes and cationic gallenium species in the case of larger metal bases. The results suggest the predominance of steric bulk in controlling the outcome of group 13 trihalide Lewis acid additions to metal bases.

Full text of DOI:10.1021/acs.organomet.6b00045

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