Chemistry of Natural Compounds p. 103 - 105 (1992)
Update date:2022-08-11
Topics:
Nikolaeva, L. A.
Kovalev, B. G.
Ishchenko, R. I.
A new synthesis of nonadeca-1,cis-3,cis-6,cis-9-tetraene, the sex pheromone of the winter moth Operophtera brumata, has been developed which involves the alkylation of bromomagnesium derivatives of tetrahydropyranyl ethers of mono- and diacetylenic alcohols by a monoacetylenic bromide, followed by hydrogenation of the resulting triynol to a trienol, oxidation of the latter to an aldehyde, and interaction of the latter with methylenetriphenylphosphorane.
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