A novel preparative method for homo- and heteroannular conjugated dienes in decalin derivatives by the palladium-catalyzed regioselective elimination reaction of allylic carbonates under mild conditions

DOI: 10.1016/S0040-4039(00)92239-1

Source and publish data:

Tetrahedron Letters p. 2549 - 2552 (1992)

Update date:2022-08-16

Topics:

Authors:

Mandai, Tadakatsu

Matsumoto, Takaji

Nakao, Yoshiki

Teramoto, Hisami

Kawada, Mikio

Tsuji, Jiro

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Article abstract of DOI:10.1016/S0040-4039(00)92239-1

Homoannular conjugated dienes in decalin systems can be prepared by the palladium-catalyzed elimination reaction of α-allylic carbonates and heteroannular dienes are obtained from β-allylic carbonates.

Full text of DOI:10.1016/S0040-4039(00)92239-1

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