SYNTHESIS AND CRYSTAL STRUCTURE OF 1,1,1,5,5,5-HEXAFLUORO-2-AMINOPENTAN-4-ONE (HFAP)

Article abstract of DOI:10.1016/S0022-1139(00)80908-2

The vapour phase reaction of ammonia and hexafluoroacetylacetone leads to the formation of the new β-keto-amine C5H3F6NO.Crystals of the compound are monoclinic, space group P2₁/n, a = 10.01(2), b = 19.33(3), c = 8.40(1) Angstroem, β = 82.27(6) deg; final R = 0.044.