Journal of the Chemical Society, Dalton Transactions p. 1671 - 1676 (1995)
Update date:2022-08-29
Topics:
Masciocchi, Norberto
Moret, Massimo
Cairati, Paolo
Sironi, Angelo
Ardizzoia, G. Attilio
Monica, Girolamo La
Silver imidazolate has been synthesized and its solid-state structure determined, ab initio, from conventional X-ray powder diffraction data only.The crystals are orthorhombic, space group P212121, with a = 5.5759(4), b = 6.7452(4), c = 22.174(1) Angstroem, U = 834.0(1) Angstroem3, Z = 8, Dc = 2.786 g cm-3.The structure was solved by a real-space scavenger technique and refined by the Rietveld method down to Rp and RF values of 0.062 and 0.027, respectively, for 4401 data points (1262 reflections) measured at room temperature in the 17-105 deg (2θ) range.The crystal structure of <a complex packing of polymeric chains folding about the crystallographic c axis, containing linearly co-ordinated silver atoms joined by imidazolate fragments.Short interchain Ag...Ag contacts <3.161(4) Angstroem> were observed.
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