Chemical Communications p. 3974 - 3976 (2018)
Update date:2022-08-11
Topics:
Pfrunder, Michael C.
Brock, Aidan J.
Brown, Joshua J.
Grosjean, Arnaud
Ward, John
McMurtrie, John C.
Clegg, Jack K.
The rational, deliberate design of supramolecular architectures is of great importance for the discovery of complex materials. A three-dimensional cubic halogen-bonded network has been prepared by combination of an octahedral metal-containing halogen bond acceptor and a linear ditopic donor. This material displays α-Po pcu topology and is seven-fold interpenetrated. This is the first neutral, metal-containing three-dimensional halogen-bonded network to be reported.
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