The behaviour of medium-sized permethylated cyclosilanes towards SOCl2 and SOCl2-HC(OCH3)3

DOI: 10.1016/0022-328X(92)83081-R

Source and publish data:

Journal of Organometallic Chemistry p. 161 - 164 (1992)

Update date:2022-08-11

Topics:

Authors:

Jenkner, P.K.

Spielberger, A.

Hengge, E.

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/0022-328X(92)83081-R

Treatment of Si6Me12 with SOCl2 in various solvents gives α,ω-dichloropermethylpolysilanes (n_Si = 2,3,4,6) at temperatures above 80 deg C.In contrast to an earlier report, treatment of the α,ω-dichloropermethylpolysilanes with HC(OCH3)3 in the presence of SOCl2 does not give Si6Me12.

Full text of DOI:10.1016/0022-328X(92)83081-R

Products guided by the article

Product name:1,2-Dichlorotetramethyldisilane

Cas No:4342-61-4

R&D Labs maybe for 4342-61-4

HEBEI BRANT PHARMACEUTICAL

Contact:+86-0311-84455288-844

Address:Mayu Industrial Park, Jinzhou, Hebei, China.
Aqua Chem Industry Co., Ltd

Contact:+86-515-88356562

Address:No.2, West Daqing Road, Yancheng, Jiangsu, China
SHANDONG QINGYUNCHANGXIN CHEMICAL SCIENCE-TECH CO.,LTD

Contact:86-21-60560171

Address:1689Donghuan Rade,Qingyun County, Dezhou City, Shandong,China
Meryer (Shanghai) Chemical Technology Co., Ltd.

website:http://www.meryer.com/cn/index/

Contact:+86-755-86170518

Address:Minhang,Shanghai, China
WUXI KINGHAN BIO-MEDICAL&CHEMICAL INC.

Contact:13861062998

Address:Room 1316,No.1619 Huishan Avenue,Wuxi,China

Relevant to this article

Doi:10.1021/acs.orglett.8b01901
(2018)
Structure Sensitivity of the Catalytic Oxidation of n-Butane to Maleic Anhydride

Doi:10.1039/c39850000492
(1985)
HYDROGENOLYSIS AND HOMOLOGATION OF LINEAR AND BRANCHED PENTENES ON Ru/SiO₂ CATALYSTS: IMPLICATION IN THE MECHANISM OF C-C BOND FORMATION AND CLEAVAGE ON METAL SURFACES.

Doi:10.1021/ja00209a043
(1988)
Efficient oxidation of sulfur mustard and its simulants using N-tert-butyl-N-chlorocyanamide

Doi:10.1080/00397910600640370
(2006)
Rate enhancement by ethylene in the ru-catalyzed ring-closing metathesis of enynes: Evidence for an "ene-then-yne" pathway that diverts through a second catalytic cycle

Doi:10.1002/anie.200502243
(2005)
Doi:10.1016/S0040-4039(01)86817-9
(1973)

Article Doi