The behaviour of medium-sized permethylated cyclosilanes towards SOCl2 and SOCl2-HC(OCH3)3

DOI: 10.1016/0022-328X(92)83081-R

Source and publish data:

Journal of Organometallic Chemistry p. 161 - 164 (1992)

Update date:2022-08-11

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Authors:

Jenkner, P.K.

Spielberger, A.

Hengge, E.

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Article abstract of DOI:10.1016/0022-328X(92)83081-R

Treatment of Si6Me12 with SOCl2 in various solvents gives α,ω-dichloropermethylpolysilanes (n_Si = 2,3,4,6) at temperatures above 80 deg C.In contrast to an earlier report, treatment of the α,ω-dichloropermethylpolysilanes with HC(OCH3)3 in the presence of SOCl2 does not give Si6Me12.

Full text of DOI:10.1016/0022-328X(92)83081-R

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