Bulletin of the Chemical Society of Japan p. 3029 - 3030 (1980)
Update date:2022-08-10
Topics:
Okubo, Masao
Morigami, Yoshiaki
Suenaga, Reiko
The effect of 2,6-dimethyl groups on enolization vs. addition in the reaction of PhMgBr with PhCH2COPh, and also the formation of α-diketone from 2,4,6-Me3C6H2COCl by the treatment with MeMgX and i-PrMgX in the presence of CoCl2, were studied.The results were discussed on the basis of electron-transfer mechanism.
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