Journal of the Chemical Society. Chemical communications p. 653 - 654 (1980)
Update date:2022-08-28
Topics:
Smith, Clifford L.
Arnett, James
Ezike, James
Deoxygenation of benzophenone, benzaldehyde, and cyclohexanone with chloromethylsilanes and zinc-copper couple in ether is reported to yield 2,2,2-triphenylacetophenone, a mixture of deoxybenzoin and diphenylacetaldehyde, and a bicyclic ketone with the proposed 2-oxocycloheptanespirocyclohexane structure, respectively; a carbene mechanism is proposed.
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