Journal of Organic Chemistry p. 1382 - 1387 (1984)
Update date:2022-08-11
Topics:
Bartmess, John E.
Burnham, Robert D.
The gas-phase acidities of a number of 2-substituted propenes have been measured by using ICR spectrometry.The acidities are rationalized in terms of structural effects on both acid and anion forms.MNDO calculations reproduce the acidities to +/-4.2 kcal/mol and provide information on the interaction of the ? orbitals of substituent and acid.
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