The ultraviolet photochemistry of condensed-phase acetyl chloride

DOI: 10.1016/S0009-2614(96)01224-9

Source and publish data:

Chemical Physics Letters p. 574 - 580 (1996)

Update date:2022-08-18

Topics:

Authors:

Rowland, Brad

Hess, Wayne P.

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Article abstract of DOI:10.1016/S0009-2614(96)01224-9

Ultraviolet (UV) irradiation of amorphous and crystalline samples of solid acetyl chloride produces metastable HC1 · ketene complexes in a 1:1 ratio following S₁ photoexcitation. The HC1 · ketene complex is the only product observed following UV irradiation of either amorphous or crystalline samples. The condensed-phase reaction mechanism contrasts starkly with that of the gas phase mechanism that produces Cl and CH₃CO radicals by prompt photolysis, followed by dissociation of internally excited CH₃CO to form CO and CH₃ in a non-concerted process.

Full text of DOI:10.1016/S0009-2614(96)01224-9

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