Ruthenium-catalyzed cytochrome P-450 type oxidation of alkanes with alkyl hydroperoxides

DOI: 10.1016/S0040-4039(00)91779-9

Source and publish data:

Tetrahedron Letters p. 1299 - 1302 (1993)

Update date:2022-08-16

Topics:

Authors:

Murahashi

Oda Oda

Naota Naota

Kuwabara

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Article abstract of DOI:10.1016/S0040-4039(00)91779-9

The ruthenium-catalyzed oxidation of alkanes with t-butyl hydroperoxide under mild conditions gives the corresponding ketones and alcohols highly efficiently. Kinetic study revealed that the reaction involves hydrogen abstraction of oxoruthenium species.

Full text of DOI:10.1016/S0040-4039(00)91779-9

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