Retro Abramov vs. Rearrangement path competition in hydroxyphosphonate decomposition

Article abstract of DOI:10.1080/10426500008042095

1-hydoxyphosphonates in the presence of aliphatic amine undergo two competitive processes: retro Abramov reaction and intramolecular hydroxyphosphonate-phosphate rearrangement. Both reaction rates and their ratio strongly depend on the nature of the substituent on a alpha carbon atom. Kinetic experiments indicate that two reactions proceed via common transition state.

Full text of DOI:10.1080/10426500008042095

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Phosphorus, Sulfur, and Silicon
and the Related Elements
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RETRO ABRAMOV VS.
REARRANGEMENT
PATH COMPETITION IN
HYDROXYPHOSPHONATE
DECOMPOSITION
a
b
Roman Gancarz , Irena Gancarz & Agnieszka Deron
a
a
Institute of Organic Chemistry, Biochemistry and
Biotechnology, Wybrźe Wyspiańskiego 27, 50-370,
Wroczaw, Poland
b
Institute of Organic Technology and Plastics,
Technical University of Wrochw, Wybrźe
Wyspiańskiego 27, 50-370, Wroczaw, Poland
Version of record first published: 04 Oct 2006
To cite this article: Roman Gancarz, Irena Gancarz & Agnieszka Deron (2000): RETRO
ABRAMOV VS. REARRANGEMENT PATH COMPETITION IN HYDROXYPHOSPHONATE
DECOMPOSITION, Phosphorus, Sulfur, and Silicon and the Related Elements, 161:1,
61-69
To link to this article: http://dx.doi.org/10.1080/10426500008042095
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