Homolytic aromatic substitutions of pentatomic heteroaromatics with electrophilic carbon radicals generated by alkyl halides and triethylborane

DOI: 10.1016/S0040-4039(00)74072-X

Source and publish data:

Tetrahedron Letters p. 5015 - 5018 (1993)

Update date:2022-08-17

Topics:

Authors:

Baciocchi

Muraglia

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Article abstract of DOI:10.1016/S0040-4039(00)74072-X

An efficient homolytic aromatic substitution of pyrroles, furan and thiophene by ·CH₂CO₂Et and ·CH(CH₃)CO₂Et has been carried out the radicals being generated by autoxidation of BEt₃ in the presence of XCH₂CO₂Et and XCH(CH₃)CO₂Et(X=Br, I).

Full text of DOI:10.1016/S0040-4039(00)74072-X

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