Bulletin of the Chemical Society of Japan p. 2297 - 2298 (1982)
Update date:2022-08-16
Topics:
Kagayama, Takashi
Okabayashi, Shinji
Amaike, Yoichi
Matsukawa, Yasuo
Ishii, Yasutaka
Ogawa, Masaya
cis-Bicyclo<4.3.0>nona-3,7-diene (1) was catalytically disproportionated by the use of Fe(CO)5 and Cp2Fe2(CO)4 to bicyclo<4.3.0>non-1(6)-ene (3) and indan (4).However, the same reaction catalyzed by the use of other metal carbonyls gave merely small amount of 3 and 4, while those using Pd- and Rh-carbons yielded only 4 and the starting material, 1, respectively.
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