Journal of the Chemical Society. Chemical communications p. 284 - 285 (1984)
Update date:2022-08-24
Topics:
Mulliez, Michel
Majoral, Jean-Pierre
Bertrand, Guy
Irradiation of azidophosphonium salts (Me2N)3P+N3,X- (1; X = PF6) and (4; X = Br) leads either to an iminophosphonium salt (Me2N)2P+=N-NMe2,PF6- (2) or to an iminophosphorane (Me2N)3P=NH (7) depending on the nature of the anion; these differences in the photochemical behaviour of (1) and (4) are rationalized by the transient existence of a phosphonitrenium salt (Me2N)3P=N+,X- (8).
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