Journal of the Chemical Society. Chemical communications p. 1583 - 1585 (1989)
Update date:2022-08-31
Topics:
Botting, Nigel P.
Jackson, Alan A.
Gani, David
The mechanism of the L-threo-3-methylaspartase ammonia-lyase reaction has been investigated using double isotope (2H/1H, 15N/14N) fractionation techniques; the physiological substrate is deaminated via a concerted mechanism in which Cβ-H and Cα-N bond cleavage occur in the same transition state.
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Doi:10.1021/ol0486932
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